It was established that at the cathodic treatment of titanium in aqueous dimethyl sulfoxide solutions of sodium molybdate, containing phosphoric acid, at the potential of the cathodic incorporation of sodium (Ec = − 2.6 V) in the potentiostatic mode, the composition formed on the electrode surface layer depended not only on the composition of the solution, but also on the volume ratio of the aqueous electrolyte solution and the organic solvent (dimethyl sulfoxide).