Electrochemical behavior of Li[Ni1/3Co1/3Mn1/3]O2 Catode material produced by scs procedure

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DOI: 10.18500/1608-4039-2015-15-4-167-174

In this paper, we present the results of electrochemical characterisation of a Li[Ni1/3Co1/3Mn1/3]O2 cathode material prepared by the solution combustion synthesis. Initially, [CoMnNi]Ox powder was obtained by combustion of cobalt, nickel and manganese nitrate solution with glycine or both glycine and citric acid. Li[Ni1/3Co1/3Mn1/3]O2 was then synthesised by annealing of the mixed oxide powder impregnated with lithium nitrate at 920–970°C. The discharge capacity and the capacity retention of the Li[Ni1/3Co1/3Mn1/3]O2 cathodes were found to be 141–149 and 131–137 mAh• g^-1 for C/10 and C/2 rates, respectively. LISP-50 (lithium ion sealed prismatic) batteries with the Li[Ni1/3Co1/3Mn1/3]O2 cathode demonstrated during their testing that energy loss did not exceed 30% after 2000 cycles at the utilisation of 70%

Authors:

Zhuravlev Viktor Dmitrievich, Institute of Chemistry of a Solid body UB of RAS, 91, GSP, Pervomayskaya St., Yekaterinburg, 620990, zhvd@ihim.uran.ru

Bushkova Ol'ga Viktorovna, Institute of high-temperature Electrochemistry UB of RAS, 20, Akademicheskaya St., Yekaterinburg, 620990, ovbushkova@rambler.ru

Pachuev Andrey Viktorovich, JSC Saturn, 21, p. 1, B. Cherkizovskaya St., Moscow, 107553, sector211@geo.kuban.ru

Nefedova Kseniya Valer'evna, Institute of Chemistry of a Solid body UB of RAS, 91, GSP, Pervomayskaya St., Yekaterinburg, 620990, nefedova@ihim.uran.ru

Key words:

cathode material Li[Ni1/3Co1/3Mn1/3]O2, solution combustion synthesis, cycling, electrochemical properties

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Journal issue:

2015. Т. 15, № 4,

Heading:

Lithium electrochemical systems

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