Study of thin-film electrodes of the system Si–Al–O for lithium-ion battery

Structure of thin-film electrodes manufactured by layer-by-layer magnetron sputtering of Si and Al in the environment with small oxygen additives has been studied. Charge-discharge behavior of these electrodes was studied as well. It is shown that such electrodes are able to stable cycling with marginal irreversible capacity.

Authors:

Kulova Tat'yana L'vovna, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS, 31, Leninsky Ave, Moscow, 119071, tkulovat@mail.ru

Skundin Aleksandr Mordukhaevich, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS, 31, Leninsky Ave, Moscow, 119071, askundin@mail.ru

Andreev Vladimir Nikolaevich, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS, 31, Leninsky Ave, Moscow, 119071, vandr@phyche.ac.ru

Gryzlov Dmitrii Yur'evich, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS, 31, Leninsky Ave, Moscow, 119071, 6u2008@yandex.ru

Mironenko Aleksandr Aleksandrovich, Yaroslavl Branch of Federal State Budgetary Institution of Science of RAS Physicotechnological Institute, 21, Universitetskaya St., Yaroslavl, 150007, amironenko55@mail.ru

Rudyi Aleksandr Stepanovich, Yaroslavl Branch of Federal State Budgetary Institution of Science of RAS Physicotechnological Institute, 21, Universitetskaya St., Yaroslavl, 150007, rudy@uniyar.ac.ru

Gusev Valerii Nikolaevich, Yaroslavl Branch of Federal State Budgetary Institution of Science of RAS Physicotechnological Institute, 21, Universitetskaya St., Yaroslavl, 150007

Naumov Viktor Vasil'evich, Yaroslavl Branch of Federal State Budgetary Institution of Science of RAS Physicotechnological Institute, 21, Universitetskaya St., Yaroslavl, 150007, vvnau@rambler.ru

Key words:

lithium-ion battery, amorphous silicon, Si–Al–O system, degradation, irreversible capacity

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Journal issue:

2013. Т. 13, № 3,

Heading:

Lithium electrochemical systems

DOI:

https://doi.org/10.18500/1608-4039-2013-13-3-136-143

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