Silicon electrodes degradation at cycling | Elektrokhimicheskaya Energetika (Electrochemical Energetics)

On basis of analysis of literature data as well as of own experimental results we suggest some regularity for degradation of silicon electrodes upon cycling. It was shown that an electrode capacity Q at n-th cycle can be calculated from equation Q = Q₀ exp(kn+βn²/2), where Q₀ is initial capacity value, k и β are empiric constants.

Authors:

Galperin Valerii Aleksandrovich, Institute of Nanotechnologies of Microelectronics of RAS, 32a???, Leninsky Ave, Moscow, 119991, v.galperin@tcen.ru

Kitsyuk Evgenii Pavlovich, Technological Center Scientific-industrial Complex of MIET, 5, ave. 4806, Moscow, Zelenograd, 124498, Hedgeshot@gmail.com

Kulova Tat'yana L'vovna, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS, 31, Leninsky Ave, Moscow, 119071, tkulovat@mail.ru

Skundin Aleksandr Mordukhaevich, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS, 31, Leninsky Ave, Moscow, 119071, askundin@mail.ru

Tuseeva Elena Konstantinovna, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS, 31, Leninsky Ave, Moscow, 119071, elenatusseeva@mail.ru

Key words:

lithium-ion batteries, silicon electrodes, degradation

Literature

1. Галперин В. А., Кицюк Е. П., Скундин А. М., Тусеева Е. К., Шаман Ю. П., Скорик С. Н. // Изв. вузов. Электроника. 2013. № 4. С. 38–43.
2. Галперин В. А., Павлов А. А., Шаман Ю. П., Шаманаев С. В., Шулицкий Б. Г. // Инновационные технологии. / под ред. проф. С. В. Булярского, Ульяновск: УлГУ. 2010. № 3. С. 196–202.
3. Bourderau S., Brousse T., Schleich D. M. // J. Power Sources. 1999. Vol. 81–82. P. 233–236.
4. Rousselot S., Gauthier M., Mazouzi D., Lestriez B., Guyomard D., Rouй L. // J. Power Sources. 2012. Vol. 202. P. 262–268.

Heading:

Lithium electrochemical systems

DOI:

https://doi.org/10.18500/1608-4039-2013-13-2-59-63

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