The kinetic of lithium ions intercalation in the anatase synthesized by sol-gel methods | Elektrokhimicheskaya Energetika (Electrochemical Energetics)

Possibility of ultradispersed TiO₂2 (anatase modification) using as the base of the lithium power sources cathode material obtained by chloride-acid hydrolysis of titanium tetrachloride has been studied. The researches of Li+ ions electrochemical intercalation kinetics and phasic model of the process was suggested. The cathode material phase composition changes during discharge were fixed and interpreted.

Authors:

Kotsyubinskii V. O., Carpathian National University of V. Stefanik, 57, Shevchenko St., Ivano-Frankovsk, 76025

Chelyadyn V. L., Carpathian National University of V. Stefanik, 57, Shevchenko St., Ivano-Frankovsk, 76025

Il'nitskii R. V., Carpathian National University of V. Stefanik, 57, Shevchenko St., Ivano-Frankovsk, 76025

Mironyuk I. F., Carpathian National University of V. Stefanik, 57, Shevchenko St., Ivano-Frankovsk, 76025

Moklyak V. V., Institute of Metallophysics of G. V. Kurdyumov NAN of Ukraine, 36, boulevard of the academician Vernadsky, Kiev, 3680

Kolkovskii P. I., Carpathian National University of V. Stefanik, 57, Shevchenko St., Ivano-Frankovsk, 76025

Key words:

литиевый источник тока, ультрадисперсный анатаз, диффузия ионов лития, деструкция электролита

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Heading:

Lithium electrochemical systems

DOI:

https://doi.org/10.18500/1608-4039-2011-11-4-179-183

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