The paper considers the electrochemical properties of potassium polytitanate synthesized at the values of pH varying from 3 to 8 in a wide temperature range from − 26 to + 80°C. The conductivity values and the activation energy were determined with the help of the method of impedance spectroscopy. The application of the obtained material used as a ceramic solid electrolyte in the energy storage units operating at low temperatures in the Far North is considered in the article.