Cd|KOH|NiOOH

Zn|NH4CI|MnO2

Li|LiClO4|MnO2

Pb|H2SO4|PbO2

H2|KOH|O2

гидролизный лигнин

Graphite Bisulphate and Thermal Expanded Graphite from Lignin

Pathbreaking studies of electrochemical graphite bisulphate synthesis from artificial graphite produced from hydrolyzed lignin and further production of high quality thermal expanded graphite are described. The studies show that any oxidation level can be achieved as well as over oxidized graphite may be produced at graphite bisulphate synthesis. Parameters of graphite bisulphate synthesis and thermal expanded graphite parameters are close to those of graphite bisulphate and thermal expanded graphite produced from natural graphite's. The article also describes results of microstructure and element analysis of thermal expanded graphite as well as its granulometric composition. The product is promising as a component of active masses for electrodes of chemical sources of current.

The lithium batteries based on the gidrolytic lignin

In this paper the possibility of applying of hydrolysis lignin as the lithium battery cathode material was demonstrated for the first time. Hydrolysis lignin features have been investigated by impedance spectroscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. Electrochemical characterization was carried out at room temperature using 1M LiBF4 in γ-butyrolacton electrolyte system. The chemical composition of cathode materials upon battery discharge down to 0.9 V was studied by the X-ray photoelectron spectroscopy and Infrared spectroscopy. The suggestions on possible electrochemical reactions occurring in the lithium/hydrolysis lignin system were made on the basis of the products composition analysis.