The dynamic character of processes taking place at aging of electrodes based on silicon composites

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).

УДК 544.65+621.355.9

DOI: https://doi.org/10.18500/1608-4039-2016-16-1-3-9

The aging behaviour of thin-film multi-layered electrodes consisting from alternating layers of Si-O and Si-O-Al has been studied with using of electrochemical impedance spectroscopy (EIS). The equivalent circuit comprising weak inductance, ohmic resistance, and three parallel combinations of resistance and \text{CPE was proposed. The most interesting feature of the EIS data is non-monotonous change equivalent circuit components during the storage. This fact testifies dynamic character of SEI which manifests itself not only at the cycling but at OCP storage as well.

Authors:

Kulova Tat'yana L'vovna, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS, 31, Leninsky Ave, Moscow, 119071, tkulovat@mail.ru

Emets Viktor Vladimirovich, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS, 31, Leninsky Ave, Moscow, 119071, ictoremets@mail.ru

Skundin Aleksandr Mordukhaevich, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS, 31, Leninsky Ave, Moscow, 119071, askundin@mail.ru

Key words:

electrochemical impelance spectroscopy; silicon composites; processes at electrode aging

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Journal issue:

2016. Т. 16, № 1,

Heading:

Lithium electrochemical systems

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