Полимерные связующие для электродов литиевых аккумуляторов. Часть 2. Синтетические и природные полимеры

Статья опубликована на условиях лицензии Creative Commons Attribution 4.0 International (CC-BY 4.0).

Во второй части обзора обсуждаются перспективы использования альтернативных полимерных связующих для композиционных электродов литиевых электрохимических систем. Среди возможных вариантов рассмотрены наиболее популярные коммерчески доступные синтетические полимеры с функциональными группами (преимущественно образующие водные растворы или дисперсии) и водорастворимые полимеры природного происхождения. Отличительной чертой таких материалов является их многофункциональность. Доступность солевых форм для природных и синтетических полимеров, многие из которых являются полиэлектролитами, позволяет оказывать значительное влияние на ионный перенос в композиционной электродной массе, снижая поляризацию электродов и улучшая мощностные характеристики аккумуляторов. Способность образовывать «искусственный SEI» и/или формировать трёхмерную сетку с самовосстанавливающимися поперечными связями между макромолекулами делает возможным длительное безопасное циклирование, что особенно важно для активных материалов с очень большими изменениями объёма при интеркаляции/деинтеркаляции лития (например, кремния).

Авторы:

Истомина Айгуль Салаватовна, Институт химии твёрдого тела УрО РАН, 620990, г. Екатеринбург, ГСП, ул. Первомайская, 91, istominaaigul@gmail.com

Бушкова Ольга Викторовна, Институт высокотемпературной электрохимии УрО РАН, 620990, г. Екатеринбург, ул. Академическая, 20, ovbushkova@rambler.ru

Ключевые слова:

полимерные связующие, полиэлектролиты, искусственный SEI, композиционные электроды, литий-ионные аккумуляторы

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2020. Т. 20, № 4,

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