Легированный марганцем диоксид титана с улучшенными электрохимическими характеристиками для литий-ионных аккумуляторов
В работе изучен механизм влияния примеси марганца на электрохимические характеристики диоксида титана в модификации анатаз (Mn/Ti = 0.05; 0.1; 0.2). Установлено, что введение Mn3+ в структуру TiO2 приводит к образованию твердого раствора Ti1 − xMnxO2 и сопровождается увеличением объема элементарной ячейки с 136.41 Å3 (недопированный образец) до 137.25 Å3 (Mn/Ti = 0.05). Для легированного TiO2 обнаружено повышение электропроводности приблизительно на два порядка. На электроде из Ti0.95Mn0.05O2 зафиксирована ёмкость 186 мА⋅ч/г после 30 циклов заряда/разряда в режиме C/10, что выше чем для недопированного TiO2 (87 мА⋅ч/г) В условиях повышенной токовой нагрузки 2С легированный диоксид титана (Mn/Ti = 0.05) сохраняет обратимую ёмкость около 121 мА⋅ч/г.
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